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  • Alkali metal salts of 1,2,3-benzodiazaborines: Platforms for late-stage N-functionalization and metal complexation
    by Leonie WĂĽst
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01395J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leonie WĂĽst, Lea Scheuring, Tim Wellnitz, Krzysztof Radacki, Holger BraunschweigThe standard procedure for the preparation of benzoid 1,2,3-diazaborines (DABs) is the condensation of 2-formylphenyl boronic acid with a hydrazine. The choice of hydrazine derivative irreversibly predetermines the N-substituent in…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Photoinduced carbonylative annulation access to β-lactams
    by Yuanrui Wang
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02418H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuanrui Wang, Xin Qi, Zhipeng Bao, Xiao-Feng WuIn radical carbonylation chemistry, orderly and sequential construction of C-C and C-N bonds with CO can effectively approach amide units and quickly incorporate a wide range of functional groups. However,…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Enabling uniform lithiation in solid-state synthesis by preventing pre-matured surface grain coarsening through grain boundary engineering
    by Yifan Wu
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00271K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yifan Wu, Xincan Cai, Weiyi Lin, Yingdong Deng, Qing Zhang, Haoyuan Li, Pu Yan, Guohui Zhong, Jin XieSolid-state calcination profoundly influences the structural integrity and electrochemical performance of polycrystalline layered oxide cathode materials in lithium-ion batteries. As temperatures rise, heterogeneous phase transitions driven by solid-state diffusion can…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Critical issues and optimization strategies of vanadium dioxide-based cathodes towards high-performance aqueous Zn-ion batteries
    by Botao Wan
    Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01889G, Review Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Botao Wan, Yajiang Wang, Xiudong Chen, Changchao Zhan, Huixiong Jiang, Jin-Hang Liu, Yun Gao, Xiaoduo Jiang, Xiaohua Cao, Hang Zhang, Shi-Xue Dou, Yao XiaoAqueous zinc-ion batteries (AZIBs) are gaining significant attention due to their excellent safety, cost-effectiveness, and environmental friendliness, making them highly competitive energy storage solutions.To cite this article before page numbers are assigned, use the DOI […]
  • Affinity peptide ligands: new tools for chasing non-canonical N-phosphoproteome
    by He Wang
    Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01557J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.He Wang, Xiaoyu Zhang, Dongdong Wang, Qianqian Jiang, Yue Sun, Baofeng Zhao, Zhen Liang, Guangyan Qing, Bo Jiang, Lihua Zhang, Yukui ZhangThis work proposed an organic solvent- and metal-free N-phosphorylation enrichment strategy based on affinity peptides identified by phage display, allowing elucidation of global N-phosphoproteome with high efficiency, selectivity and robustness.To cite this article before page numbers are […]
  • α-N-Phthalimido-Oxy Isobutyrate-Mediated Deoxygenative Arylation: Total Synthesis of Alanenses A and B
    by Young Eum Hyun
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00341E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Young Eum Hyun, Jeonguk Kweon, Thi Hieu Linh Phan, Dongwook Kim, Sunkyu HanInspired by our biosynthetic hypothesis for alanense A, we developed two distinct methods for the deoxygenative arylation of α-N-phthalimido-oxy isobutyrate (NPIB), derived from hydroxyl groups adjacent to or conjugated with…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Single-Molecule Nanopore Sensing of Proline cis/trans Amide Isomers
    by Luca Iesu
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01156F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Luca Iesu, Mariam Sai, Vladimir Torbeev, Bruno Kieffer, Juan Pelta, Benjamin CressiotMolecules known as stereoisomers possess identical numbers and types of atoms, which are oriented differently in space. Cis-trans isomerization of proline, a distinctive case of stereoisomerism in peptides and proteins,…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Correction: Advanced fabrication techniques for polymer–metal nanocomposite films: state-of-the-art innovations in energy and electronic applications
    by Muhammad Tayyab
    Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC90087E, Correction Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Tayyab, Liu Zizhe, Sajid Rauf, Zixuan Xu, R. U. R. Sagar, Faisal Faiz, Zuhra Tayyab, Rashid Ur Rehman, Muhammad Imran, Anjam Waheed, Rida Javed, A. Surulinathan, Zulakha Zafar, Xian-Zhu Fu, Jing-Li LuoTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
  • Icosahedron kernel defect in Pt1Agx series of bimetallic nanoclusters enhances photocatalytic hydrogen evolution
    by Dong Tan
    Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC01735A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dong Tan, Tengfei Ding, Kaidong Shen, Chang Xu, Shan Jin, Daqiao Hu, Song Sun, Manzhou ZhuThe novel Pt1Ag11 nanocluster with a defect-containing icosahedral kernel displayed excellent catalytic performance in the photocatalytic hydrogen evolution reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society […]
  • An overlooked cyclase plays a central role in the biosynthesis of indole diterpenes
    by Rosannah Cameron
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02009C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rosannah Cameron, Daniel Berry, Alistair T. Richardson, Luke J. Stevenson, Yonathan Lukito, Kelly Styles, Natasha S. L. Nipper, Rose May McLellan, Emily ParkerIndole diterpenes (IDTs) are a large class of highly complex fungal natural products that possess a wide array of intriguing bioactivities. While IDTs are structurally diverse, the first four steps…The content of this RSS Feed (c) […]
  • Switching Mesoionic Carbene-Organocatalysis from Radical to Ionic Pathway through Base-Controlled Formation of Breslow Intermediates versus Breslow Enolates
    by Jie Jiao
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08229J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jie Jiao, Zengyu Zhang, Guangyin Lu, Shiqing Huang, Yajing Bian, Fan Gao, Guy Bertrand, Xiaoyu YanN-Heterocyclic carbene (NHC) organocatalysis has experienced significant advancements. Two distinct reaction pathways have been developed, ionic and radical, through Breslow intermediates (BIs) and Breslow enolates (BI-s), respectively. The ability to…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Catalytic Alkoxysilylation of C–H bonds with tert-Butyl-Substituted Alkoxysilyldiazenes
    by Lamine Saadi
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02059J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lamine Saadi, LoĂŻc Valade, ClĂ©ment ChauvierOrganoalkoxysilanes (e.g. R–SiMe3-n(OR’)n, 1 ≤ n ≤ 3 with R=alkyl or aryl) have found various applications in synthetic chemistry and materials science because the silicon-bound alkoxy groups provide unique opportunities…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Tandem Reaction-Powered Near-Infrared Fluorescent Molecular Reporter for Real-Time Imaging of Lung Diseases
    by Yan Hu
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01488C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yan Hu, Hongshuai Zhang, Yiteng Ding, Weirui Chen, Changqie Pan, Longwei He, Dan Cheng, Lin YuanDiabetes and its complications have drawn growing research attention due to their detrimental effects on human health. Although optical probes have been used to help understand many aspects of diabetes,…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Mechanism-Guided Descriptor for Hydrogen Evolution Reaction in 2D Ordered Double Transition-Metal Carbide MXenes
    by Junmei Du
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08725A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Junmei Du, Yifan Yan, Jiao Chen, Xiumei Li, Chunsheng Guo, Yuanzheng Chen, Hongyan WangSelecting effective catalysts for the hydrogen evolution reaction (HER) among MXenes remains a complex challenge. While machine learning (ML) paired with density functional theory (DFT) can streamline this search, issues…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Water-Accelerated Photooxidation and Degradation of Lignin Linkages Mediated by Plasmonic Catalysts
    by Juhee Ha
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC08401B, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juhee Ha, Jiwon Kang, Suk Hyun Lim, Dae Won Cho, Kwang-Im Oh, Youngsoo KimThe selective oxidation and degradation of lignin are crucial for realizing its potential as a biofuel or petroleum substitute. Despite the importance of C–C bond cleavage for lignin valorization, this…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Towards Site-specific Manipulation in Cysteine-mediated Redox Signaling
    by Jing Yang
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC02016F, Perspective Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing YangCysteine sulfenic acid (SOH) modifications are pivotal in redox signaling, yet establishing their causal biological roles remains challenging due to methodological limitations. Traditional approaches often lack precision or disrupt non-redox…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Hydrogen Production via Photocatalytic Ammonia Decomposition
    by Qijun Pei
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01834J, Review Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qijun Pei, Yongyu Wang, Khai Chen Tan, Jianping Guo, Teng He, Ping ChenAmmonia, as a carbon-free fuel and promising hydrogen carrier, has attracted significant attention in the context of a net-zero-emission scenario. Photocatalytic ammonia decomposition is a promising approach for hydrogen production,…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Stomata biosilica and equisetum photosynthesis: ionic tomography insight using PDMPO silicaphilic probe
    by Victor V Volkov
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07973F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Victor V Volkov, Graham Hickman, Carole Celia PerryConfocal microscopy using silicaphilic molecular probes is a promising approach to identify the ionic character of silica interfaces. Using ab initio and density functional theory we model the structural and…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Post-coordination of Ru(II) Controlled Regioselective B(4)–H Acylmethylation of o-Carboranes with Sulfoxonium Ylides
    by Hou-Ji Cao
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC01576F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hou-Ji Cao, Jia-Xin Li, Jia-Hui Yan, Miao-Xin Liu, Qianyi Zhao, Jie Zhang, Ju Zhang, Hong YanDespite significant progress in the B–H functionalization of carboranes, the development of cost-effective catalytic systems devoid of noble metals, coupled with mechanistic validation of regioselectivity control, remains a formidable challenge….The content of this RSS Feed (c) The Royal Society of Chemistry
  • Vacuum evaporation-assisted reaction: sustainable solution for application of rare earth-based halide solid-state electrolytes
    by Zhichao Zeng
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC00003C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhichao Zeng, Xiaomeng Shi, Hongtu Zhang, Yaping DuAll-solid-state lithium-ion batteries (ASLIBs) are important and promising electric energy storage devices with high stabilities and energy densities. As burgeoning key materials in ASLIBs, rare earth (RE) halide solid-state electrolytes…The content of this RSS Feed (c) The Royal Society of Chemistry

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