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  • Organo-catalyzed photoelectrochemical ring-contraction of arylidenecyclobutanols via radical cation-triggered semipinacol rearrangement
    by Yu Zheng
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07637D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yu Zheng, Chunxi Chen, Xuhao Zhou, Guoyang Deng, Yanju Lu, Shenlin HuangThe semipinacol rearrangement has proven to be an efficient strategy for converting allylic alcohols into carbonyl compounds bearing an α-quaternary carbon center. Traditionally, this semipinacol rearrangement is initiated through two…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Dual Activation of CO₂ and N₂ Facilitated by Single Ta4+ Clusters
    by Yifan Gao
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06899A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yifan Gao, Ran Cheng, Klavs Hansen, Zhixun LuoGoverning molecular activation and reaction selectivity is a fundamental strategy for advancing catalytic performance. Metal clusters show great promise for critical reactions due to their unique electronic structures, yet the…The content of this RSS Feed (c) The Royal Society of Chemistry
  • High-Performance Narrowband Blue Electroluminescence with EQE Approaching 20% Based on Hybridized Local and Charge-Transfer Multi-Resonant Molecules
    by Huihui Li
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06259D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Huihui Li, Jiayi Qin, Taotao Ma, Jiajie Zeng, Ziwei Chen, Yan Fu, Hua Lu, Zujin Zhao, Xin Jiang FengDesigning multi-resonant (MR) materials that integrate narrowband emission and efficient exciton utilization remains challenging, especially for indolocarbazole (ICz) cores. To address this, two novel ICz-derived MR emitters, 4CzmICz and 4CzpICz,…The content of this RSS Feed (c) The Royal Society of […]
  • Thinking Outside the Library: Cluster Synthesis of Diverse Molecules on a Single Robotic Platform
    by Franck Le Vaillant
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07668D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Franck Le Vaillant, Luidgi Gromat, ClĂ©mentine Pescheteau, Nicolas Ducrot, AurĂ©lien Demilly, Jean-Christophe Meillon, Nicolas Do Huu, Quentin PerronThe development of a general autonomous platform for organic synthesis that enables faster, flexible and efficient delivery of target molecules is an attractive strategy for many fields such as drug…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Single-cell Metabolic Accumulation Analysis by Microfluidic Hydrogel Microspheres Combined with Mass Spectrometry
    by Gaowa Xing
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC05261K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gaowa Xing, Hongren Yao, Zengnnan Wu, Yuxuan Li, Ying Hou, Jin-Ming LinMetabolic analysis of tumor cells is crucial for understanding tumor metabolic reprogramming, and single-cell metabolic accumulation studies provide precise insights into tumor biology. In this work, we established a microfluidic…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Interfacial Polarization Enables Dual Pathways for Electrosynthesis of Propyl Acetate
    by Xichang Liu
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC08178E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xichang Liu, Yimin Jiang, Wei Chen, Jixiang Wu, Yongmin He, Yu-Cheng Huang, Ying-Rui Lu, Yansong Zhou, Shuangyin WangThe direct electrosynthesis of value-added esters from carbon monoxide (CO) represents a promising strategy for sustainable carbon utilization. In this study, we report the propyl acetate synthesis with a Faradaic…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Understanding Self-Assembly across Scales in BODIPY Derivatives: from Supramolecular Aggregation in Solution to Optical-Waveguiding Crystalline Materials
    by Marina GonzĂĄlez SĂĄnchez
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07776A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marina GonzĂĄlez SĂĄnchez, Ana M. Garcia, Jorge Santos Valera, Ana MarĂ­a RodrĂ­guez, Juan Cabanillas, Pilar Prieto, David Gonzalez RodriguezMolecular self-assembly constitutes a useful tool to construct discrete and functional nanostructures with well-defined properties. Nevertheless, understanding supramolecular order both in solution and in the solid state for the same…The content of this RSS Feed (c) The Royal Society of […]
  • Sequential Ag doping of Au25- atomically precise nanoclusters induces alternating positive and negative shifts of the HOMO-LUMO gap
    by Jonathan W. Fagan
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06264K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jonathan W. Fagan, Nabiha Syed, Wangshu Wen, Hanna Morales Hernandez, Alvaro Muñoz-Castro, Christopher J. JohnsonAu25(SR)18- is the most studied atomically precise metal nanocluster and is frequently used to explore the effects of doping on nanocluster performance in a range of applications. A quantitative accounting…The content of this RSS Feed (c) The Royal Society of Chemistry
  • N-centered, yet Persistent: Isolation of N2O-Based Radicals through FLP-type Stabilization
    by Andrea Orellana Ben Amor
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC08152A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrea Orellana Ben Amor, Laure Vendier, Vincent Cesar, Vincent Maurel, Julien Andre Panetier, Nicolas QueyriauxThe electrochemical one-electron reduction of IDipp‱N₂O (IDipp = 1,3-bis(2,6diisopropylphenyl)imidazol-2-ylidene) is inherently irreversible, highlighting the short-lived nature of the corresponding radical anion. However, stabilization by Lewis acidic boranes enables electrochemically reversible…The content of this RSS Feed (c) The Royal Society of Chemistry
  • A 4,4',4''-Nitrilotriphenoxyl Radical Derived from Yang's Biradical
    by Qiong-Yan Hong
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06789H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qiong-Yan Hong, Bin Huang, Yan-Fei Niu, Cui-Hong Wang, Xiao-li Zhao, Hai-Bo Yang, Xueliang ShiPhenoxyl radicals have attracted considerable attention due to their unique electronic structures and wide-ranging applications in physics, chemistry, biology, and materials science. Herein, we report the synthesis and in-depth characterization…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Odoribacter splanchnicus Lipooligosaccharide: an uncommon structure with weak immunostimulatory activity
    by Marta Tiemblo MartĂ­n
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC08335D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marta Tiemblo MartĂ­n, Marcello Mercogliano, Kaisa Hiippala, Luca De Simone Carone, MarĂ­a AsunciĂłn Campanero-Rhodes, Maria Masiello, Alessandro Cangiano, Antonio Molinaro, Luigi Paduano, Dolores SolĂ­s, Reetta Satokari, Flaviana Di Lorenzo, Alba SilipoOdoribacter splanchnicus, a prominent member of the human gut microbiota, has emerged as a promising next-generation probiotic due to its anti-inflammatory properties and association with intestinal health. While […]
  • Switching on photoreactivity in Ti4-oxo clusters by increasing the size of 1,n-alkane diolate bridging ligands
    by Ashwani Chikara
    Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC08522E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ashwani Chikara, Alexander R. Veale, Stephen E. Brown, Jack M. Woolley, Frank De Proft, Sebastian D. PikeUV light promotes the oxidation of one end of a bridging bidentate 1,5-diolate ligand on a Ti-oxo cluster. In contrast, due to a lack of conformational flexibility, smaller diolates cannot undergo the same photoreaction mechanism.To cite this article before page numbers are […]
  • Synergistic Effect of MOF Fillers and Succinonitrile in PEO-Based Electrolytes for Long-Cycle All-Solid-State Li-CO2 Battery
    by Yilong Huang
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07513K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yilong Huang, Jinfeng Ha, Zhixin Liu, Xingyu Yu, Yin Liu, Xiaoli Fan, Xianli Huang, Jianping He, Shuping Huang, Tao WangLi-CO2 batteries have emerged as promising candidates for next-generation energy storage systems due to their ultrahigh theoretical energy density. However, some safety issues primarily arising from the volatility and leakage…The content of this RSS Feed (c) The Royal Society […]
  • The Dynamic Chemistry of the Boron-Nitrogen Bond
    by Federico Frateloreto
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07665J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Federico Frateloreto, Giorgio Capocasa, Martina De Angelis, Greta Sandri, Osvaldo Lanzalunga, Chiara Massera, Stefano Di StefanoHere we report that fully reversible B←N bond formation/cleavage is a promising tool for the achievement of dynamic libraries (DLs) of rapidly interconverting compounds. The composition of a number of…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Programmed intralayer Co and interlayer Ni atoms in a covalent organic framework for synergistic CO2 photoreduction
    by Jie-Yu Yue
    Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC08435K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jie-Yu Yue, Rui-Zhi Zhang, Xi Chen, Chengcheng Liu, Peng Yang, Bo TangBy employing an orthogonal site-encoding strategy, we developed a bimetallic TZCOF photocatalyst with distinct intralayer CoNOCl2 and interlayer NiN2Cl2 sites, achieving a CO generation rate of 13.6 mmol g−1 h−1 and 98.7% selectivity.To cite this article before page numbers are assigned, use the DOI form of citation […]
  • The Versatile World of Cumulene Chemistry
    by Abhishek Pareek
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC04462F, Review Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Abhishek Pareek, Yu Qiu, Matthew A. Johnson, Rik Tykwinski, PrzemysƂaw GaweƂDespite a history spanning over a century, cumulenes are often relegated to the realm of perceived curiosities rather than practical synthetic intermediates as result of their high intrinsic reactivity. In…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Enantioselective Synthesis of Vicinal Amino Alcohols Promoted by Fluorine-Containing Counteranions
    by Yu-Chen Yang
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC06853C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu-Chen Yang, Jia-Long Wu, Sheng-Ye Zhang, Teng Sun, Xu Liu, Yanan Zhao, Lijia WangChiral vicinal amino alcohols are pivotal building blocks in organic synthesis and pharmaceutical research. Herein, we report a chiral copper-catalyzed two-step one-pot strategy for the efficient synthesis of diaryl chiral…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Bulky alkali metal cations enabled highly efficient iridium-catalyzed asymmetric hydrogenation for C–N axial chirality via dynamic kinetic resolution
    by Xianghua Zhao
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC08462H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xianghua Zhao, Xinyu Chen, Linxian Fan, Yulong Jiang, Yirui Chen, Dingguo Song, Fei Ling, Junyuan Hu, Weihui ZhongThe addition of excess alkali metal to Noyori-type catalysts (HM-NH) generates anionic species (HM-NM’), which significantly enhances both the reaction rate and turnover number (TON) in asymmetric hydrogenation. However, such…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Near-infrared-driven photothermal atom transfer radical polymerization
    by Martyna Cybularczyk-Cecotka
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07153D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Martyna Cybularczyk-Cecotka, Filip Bandalewicz, Wiktor Lewandowski, Grzegorz SzczepaniakReversible-deactivation radical polymerization (RDRP) is a powerful tool in modern polymer chemistry, enabling the synthesis of well-defined materials with complex architectures. Among RDRP methods, photoinduced atom transfer radical polymerization (photo-ATRP)…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Chiral Poly(aza-norbornene) Derivatives with Tunable Tacticity and Living ROMP Capability
    by Jing Bai
    Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D5SC07016C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing Bai, Yu Wang, Yi-Song Wang, Na Zhang, Xiaoyang Wang, Yan Xu, Wei YouRing-opening metathesis polymerization (ROMP) is a powerful tool to produce various polymers with diverse structures and functions, but its tacticity controllability, especially for enantio-pure monomers, is relatively unexplored. The challenge…The content of this RSS Feed (c) The Royal Society of Chemistry

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