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  • 1,5-Hydrogen Atom Transfer of α-Iminyl Radical Cations: A New Platform for Relay Annulation towards Pyridine Derivatives and Axially Chiral Heterobiaryls
    by Yu-Qiang Zhou
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01858C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu-Qiang Zhou, Kui-Cheng He, Wei-Hao Zheng, Jing-Fang Lv, Shi-Mei He, Ning Yu, Yun-Bo Yang, Lv-Yan Liu, Kun Jiang, Ye WeiThe exploitation of new reactive species and novel transformation modes for their synthetic applications have significantly promoted the development of synthetic organic methodology, drug discovery, and advanced functional materials. α-Iminyl…The content of this RSS Feed (c) The Royal Society […]
  • Highly intense NIR emissive Cu4Pt2 bimetallic clusters featuring Pt(I)-Cu4-Pt(I) sandwich kernel
    by Rui-Ru Zhong
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01022A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rui-Ru Zhong, Mo Xie, Cui-Zhou Luan, Lin-Mei Zhang , De-Bo Hao, Shang-Fu Yuan, Tao WuMetal nanoclusters (NCs) capable of near-infrared (NIR) photoluminescence (PL) are gaining increasing interest for their potential applications in bioimaging, cell labelling, and phototherapy. However, the limited quantum yield (QY) of…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Photo-Thermal Synergistic CO2 Hydrogenation towards CO over PtRh Bimetal-Decorated GaN Nanowires/Si
    by Jinglin Li
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01530D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jinglin Li, Bowen Sheng, Liang Qiu, Jiajia Yang, Ping Wang, Yixin Li, Tianqi Yu, Hu Pan, Ying Li, Muhan Li, Lei Zhu, Xinqiang Wang, Zhen Huang, Baowen ZhouPhoto-thermal-synergistic hydrogenation is a promising strategy for upcycling carbon dioxide into fuels and chemicals by maximally utilizing full-spectrum solar energy. Herein, by immobilizing Pt-Rh bimetal onto a well-developed GaN NWs/Si…The content […]
  • Optoelectronic insights of lead-free layered halide perovskites
    by Vishwadeepa Hazra
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01429D, Perspective Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vishwadeepa Hazra, Arnab Mandal, Sayan BhattacharyyaTwo-dimensional organic-inorganic halide perovskites have emerged as promising candidates for a multitude of optoelectronic technologies, owing to their versatile structure and electronic properties. The optical and electronic properties are harmoniously…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Monolithic 3D nanoelectrospray emitters based on continuous fluid-assisted etching strategy for glass droplet microfluidic chip-mass spectrometry
    by Yaoyao Zhao
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01700E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yaoyao Zhao, Ziyang Guo, Yingqi Zhao, Zhao Jin, Yaran Chang, Xiayan Wang, Guangsheng GuoGlass microfluidic chips are suitable for coupling with mass spectrometry (MS) due to their flexible design, optical transparency and resistance to organic reagents. However, due to the high hardness and…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Enantioselective synthesis of α-aryl α-hydrazino phosphonates
    by Saul Alberca
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00822G, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Saul Alberca, Javier Romero-Parra, Israel Fernandez, Rosario Fernández, Jose M. Lassaletta, David MongeCatalysts generated in situ by the combination of pyridine-hydrazone N,N-ligands and Pd(TFA)2 have been applied to the addition of arylboronic acids to formylphosphonate-derived hydrazones, yielding α-aryl α-hydrazino phosphonates in excellent…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Understanding Electrochemical Interfaces through Comparing Experimental and Computational Charge Density-Potential Curves
    by Nandita Mohandas
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00746H, Perspective Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nandita Mohandas, Sumit Bawari, Jani J.T. Shibuya, Soumya Ghosh, Jagannath Mondal, Tharangattu N. Narayanan, Angel CuestaElectrode-electrolyte interfaces play a decisive role in electrochemical charge accumulation and transfer processes. Theoretical modelling of these interfaces is critical to decipher the microscopic details of such phenomena. Different force…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Viologen-based solution-processable ionic porous polymers for electrochromic applications
    by Hongya Miao
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01408A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hongya Miao, Ling Chen, Fangfang Xing, Huijie Li, Thomas Baumgartner, Xiaoming HeA series of N-arylated viologens with terminal aldehyde groups has been synthesized. The new building blocks were successfully used to construct solution-processible, redox-active ionic porous polymers, for high-performance electrochromic films.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of […]
  • Redox regulation of Ni hydroxides with controllable phase composition towards biomass-derived polyols electro-refinery
    by Yi Tang
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01221F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi Tang, Zhuxin Gui, Yingshuai Jia, Xianping Liao, Tianlan Yan, Boxu Gao, Wenbiao Zhang, Li Chen, Qingsheng Gao, Yahong ZhangElectrocatalytic refinery from biomass-derived glycerol (GLY) to formic acid (FA), one of the most promising candidates of green H2 carrier, has driven widespread attention for its sustainability. Herein, we fabricated…The content of this RSS Feed (c) The Royal Society […]
  • Photovoltaic-driven Ni(II)/Ni(III) redox mediator for the valorization of PET plastic waste with hydrogen production
    by Jianying Wang
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01613K, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jianying Wang, Xin Li, Ting Zhang, Xinyu Chai, Mingze Xu, Menglei Feng, Chengcheng Cai, Zuofeng Chen, Xufang Qian, Yixin ZhaoA decoupling strategy involving two independent electrochemical and chemical processes was developed for upcycling PET plastic waste.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The […]
  • Padlocking dihydrofurannulation for the control of small degree of helicity built on a fused-tetracyclic core
    by Arthur Gaucherand
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC00745J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Arthur Gaucherand, Expédite Yen-Pon, Diego García-López, Jean-Valère Naubron, Sara Chentouf, Michel Giorgi, Stéphane Humbel, Marion Jean, Jean Rodriguez, Damien BonneAn organocatalyzed enantioselective domino reaction has been developed for the synthesis of configurationally locked helically chiral fused tetracyclic cores. This methodology allows the modulation of the helicity in the final molecule.To cite this article before page numbers are assigned, […]
  • Molecular mechanism of α-synuclein aggregation on lipid membranes revealed
    by Alexander J. Dear
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D3SC05661A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander J. Dear, Xiangyu Teng, Sarah R. Ball, Joshua Lewin, Robert I. Horne, Daniel Clow, Alisdair Stevenson, Natasha Harper, Kim Yahya, Xiaoting Yang, Suzanne C. Brewerton, John Thomson, Thomas C. T. Michaels, Sara Linse, Tuomas P. J. Knowles, Johnny Habchi, Georg MeislLipids are an important factor in the disease-associated aggregation of α-synuclein. Here we develop a kinetic model […]
  • Polymer design via SHAP and Bayesian machine learning optimizes pDNA and CRISPR ribonucleoprotein delivery
    by Rishad J. Dalal
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D3SC06920F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rishad J. Dalal, Felipe Oviedo, Michael C. Leyden, Theresa M. ReinekeWe present the facile synthesis of a clickable polymer library with systematic variations in length, binary composition, pKa, and hydrophobicity (clog P) to optimize intracellular pDNA and CRISPR-Cas9 ribonucleoprotein (RNP) performance.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this […]
  • Transition metal nitride catalysts for selective conversion of oxygen-containing molecules
    by William N. Porter
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC01314J, Perspective Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.William N. Porter, Kevin K. Turaczy, Marcus Yu, Hansen Mou, Jingguang G. ChenTransition metal nitrides are promising catalysts for a variety of reactions. This work outlines their use for C1 molecule upgrading, biomass valorization, and hydrogen evolution, and presents challenges and future opportunities for these catalysts.To cite this article before page numbers are assigned, use the DOI form of […]
  • Observation of Super-Nernstian Proton-Coupled Electron Transfer and Elucidation of Nature of Charge Carriers in a Multiredox Conjugated Polymer
    by Duyen K. Tran
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00785A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Duyen K. Tran, Sarah M. West, Elizabeth M. K. Speck, Samson A. JenekheNernstian proton-coupled electron transfer (PCET) is a fundamental process central to many physical and biological systems, such as electrocatalysis, enzyme operation, DNA biosynthesis, pH-/bio-sensors, and electrochemical energy storage devices. We…The content of this RSS Feed (c) The Royal Society of Chemistry
  • DNA-Directed Formation of Plasmonic Core-Satellite Nanostructures for Quantification of Hepatitis C Viral RNA
    by Samuel Mabbott
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00891J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samuel Mabbott, Siddhant Jaitpal, Ka Wai Ng, Angela Michelle San Juan, Cecilia Martinez, Christian Phillips, Sayantan TripathyHepatitis C virus (HCV) continues to be a significant public health challenge, affecting an estimated 71 million people globally and posing risks of severe liver diseases. Despite advancements in treatments,…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Halogen-Bonded Charge-Transfer Co-crystal Scintillators for High-Resolution X-ray Imaging
    by Mei-Jin Lin
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00735B, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mei-Jin Lin, Yu-Hua Chen, Guo-Zhen Zhang, Fu-Hai Chen, Shuquan Zhang, Xin Fang, Hong-Ming ChenThe development of high-quality organic scintillators encounters challenges primarily associated with the weak X-ray absorption ability resulting from the presence of low atomic number elements. An effective strategy involves the…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Copper-catalyzed Remote Double Functionalization of Allenynes
    by Shengming Ma
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC00034J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shengming Ma, Yulong Song, Chunling Fu, Jian ZhengAddition reactions of molecules with conjugated or non-conjugated multiple unsaturated C-C bonds are very attractive yet challenging due to the versatile issues of chemo-, regio-, and stereo-selectivities. Especially for the…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Boron-containing helicenes as new generation of chiral materials: opportunities and challenges of leaving the flatland
    by Agnieszka Nowak-Krol
    Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC01083C, Perspective Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Agnieszka Nowak-Krol, Patrick T. Geppert, Kenkera Rayappa NaveenIncreased interest in chiral functional dyes has stimulated activity in the field of boron-containing helicenes over the past few years. Despite the fact that the introduction of boron endows π-conjugated…The content of this RSS Feed (c) The Royal Society of Chemistry
  • Mechanochemically-induced glass formation from two-dimensional hybrid organic–inorganic perovskites
    by Chumei Ye
    Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC00905C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chumei Ye, Giulio I. Lampronti, Lauren N. McHugh, Celia Castillo-Blas, Ayano Kono, Celia Chen, Georgina P. Robertson, Liam A. V. Nagle-Cocco, Weidong Xu, Samuel D. Stranks, Valentina Martinez, Ivana Brekalo, Bahar Karadeniz, Krunoslav Užarević, Wenlong Xue, Pascal Kolodzeiski, Chinmoy Das, Philip Chater, David A. Keen, Siân E. Dutton, Thomas D. BennettWe present the crystal-glass transformation of two-dimensional hybrid […]

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