{"id":2834,"date":"1989-10-16T10:28:37","date_gmt":"1989-10-16T15:28:37","guid":{"rendered":"https:\/\/kermitmurray.com\/research\/?p=2834"},"modified":"2021-10-16T10:32:04","modified_gmt":"2021-10-16T15:32:04","slug":"infrared-spectroscopy-of-jet-cooled-transient-molecules","status":"publish","type":"post","link":"https:\/\/kermitmurray.com\/research\/1989\/10\/infrared-spectroscopy-of-jet-cooled-transient-molecules\/","title":{"rendered":"Infrared spectroscopy of jet-cooled transient molecules"},"content":{"rendered":"\n<p>R. Curl, K.K. Murray, M. Petri, M. Richnow, F. Tittel, Infrared spectroscopy of jet-cooled transient molecules, Chem. Phys. Lett., 161 (1989) 98-102; doi: <a href=\"http:\/\/dx.doi.org\/10.1016\/0009-2614(89)85038-9\">10.1016\/0009-2614(89)85038-9<\/a><\/p>\n\n\n\n<h4 class=\"wp-block-heading\">Abstract<\/h4>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"alignright is-resized\"><a href=\"https:\/\/kermitmurray.com\/research\/publications\/rice-university\/jet-radical-setup\/\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/kermitmurray.com\/research\/wp-content\/uploads\/2015\/07\/Jet-Radical-Setup.jpg\" alt=\"Pulsed valve jet-cooled radical setup\" class=\"wp-image-890\" width=\"450\" height=\"490\" srcset=\"https:\/\/kermitmurray.com\/research\/wp-content\/uploads\/2015\/07\/Jet-Radical-Setup.jpg 600w, https:\/\/kermitmurray.com\/research\/wp-content\/uploads\/2015\/07\/Jet-Radical-Setup-276x300.jpg 276w\" sizes=\"auto, (max-width: 450px) 100vw, 450px\" \/><\/a><figcaption>Pulsed valve jet-cooled radical setup: excimer laser fires toward (or across) the pulsed valve jet expansion to create radicals that are cooled in the expansion.<\/figcaption><\/figure><\/div>\n\n\n\n<p>Free radicals are produced by excimer laser flash photolysis of a suitable precursor inside the nozzle of a pulsed slit jet and cooled by supersonic expansion from the slit. The infrared spectra of the radicals are then probed by a single-frequency color-center laser. This technique has been tested on the NH<sub>2<\/sub>&nbsp;radical.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>R. Curl, K.K. Murray, M. Petri, M. Richnow, F. Tittel, Infrared spectroscopy of jet-cooled transient molecules, Chem. Phys. Lett., 161 (1989) 98-102; doi: 10.1016\/0009-2614(89)85038-9 Abstract Free radicals are produced by excimer laser flash photolysis of a suitable precursor inside the nozzle of a pulsed slit jet and cooled by supersonic expansion from the slit. The &hellip; <\/p>\n<p class=\"link-more\"><a href=\"https:\/\/kermitmurray.com\/research\/1989\/10\/infrared-spectroscopy-of-jet-cooled-transient-molecules\/\" class=\"more-link\">Continue reading<span class=\"screen-reader-text\"> &#8220;Infrared spectroscopy of jet-cooled transient molecules&#8221;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":890,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[132],"tags":[150,158],"class_list":["post-2834","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-rice","tag-excimer","tag-radical","entry"],"_links":{"self":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts\/2834","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/comments?post=2834"}],"version-history":[{"count":1,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts\/2834\/revisions"}],"predecessor-version":[{"id":2835,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts\/2834\/revisions\/2835"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/media\/890"}],"wp:attachment":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/media?parent=2834"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/categories?post=2834"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/tags?post=2834"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}