{"id":2064,"date":"2017-07-19T13:58:03","date_gmt":"2017-07-19T18:58:03","guid":{"rendered":"https:\/\/kermitmurray.com\/murray\/?p=2064"},"modified":"2024-02-20T09:34:48","modified_gmt":"2024-02-20T15:34:48","slug":"comment-on-nominal-mass","status":"publish","type":"post","link":"https:\/\/kermitmurray.com\/research\/2017\/07\/comment-on-nominal-mass\/","title":{"rendered":"Comment on: \u201cNominal Mass?\u201d"},"content":{"rendered":"\n<div class=\"wp-block-caxton-grid relative\"><div class=\"absolute absolute--fill\"><div class=\"cover bg-center absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );\"><\/div><div class=\"absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );opacity:1;\"><\/div><\/div><div class=\"relative caxton-columns caxton-grid-block\" style=\"padding-top:0;padding-left:0;padding-bottom:0;padding-right:0;grid-template-columns:repeat(12, 1fr)\" data-tablet-css=\"padding-left:em;padding-right:em;\" data-mobile-css=\"padding-left:em;padding-right:em;\">\n<div class=\"wp-block-caxton-section relative\" style=\"grid-area:span 1\/span 12\"><div class=\"absolute absolute--fill\"><div class=\"cover bg-center absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );\"><\/div><div class=\"absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );opacity:1;\"><\/div><\/div><div class=\"relative caxton-section-block\" style=\"padding-top:5px;padding-left:5px;padding-bottom:5px;padding-right:5px\" data-mobile-css=\"padding-left:1em;padding-right:1em;\" data-tablet-css=\"padding-left:1em;padding-right:1em;\">\n<p>K.K. Murray, Comment on: \u201cNominal Mass?\u201d by Athula B. Attygalle and Julius Pavlov, <em>J. Am. Soc. Mass Spectrom.<\/em> <strong>28<\/strong>, 1737-1738 (2017),<em> J. Am. Soc. Mass Spectrom. <\/em><strong>28<\/strong> (2017) 1737\u20132. doi:<a href=\"http:\/\/doi.org\/10.1007\/s13361-017-1801-1\">10.1007\/s13361-017-1801-1<\/a>.<\/p>\n<\/div><\/div>\n<\/div><\/div>\n\n\n\n<div class=\"wp-block-caxton-grid relative\"><div class=\"absolute absolute--fill\"><div class=\"cover bg-center absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );\"><\/div><div class=\"absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );opacity:1;\"><\/div><\/div><div class=\"relative caxton-columns caxton-grid-block\" style=\"padding-top:0;padding-left:0;padding-bottom:0;padding-right:0;grid-template-columns:repeat(12, 1fr)\" data-tablet-css=\"padding-left:em;padding-right:em;\" data-mobile-css=\"padding-left:em;padding-right:em;\">\n<div class=\"wp-block-caxton-section relative\" style=\"grid-area:span 1\/span 12\"><div class=\"absolute absolute--fill\"><div class=\"cover bg-center absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );\"><\/div><div class=\"absolute absolute--fill\" style=\"background-color:;background-image:linear-gradient( );opacity:1;\"><\/div><\/div><div class=\"relative caxton-section-block\" style=\"padding-top:5px;padding-left:5px;padding-bottom:5px;padding-right:5px\" data-mobile-css=\"padding-left:1em;padding-right:1em;\" data-tablet-css=\"padding-left:1em;padding-right:1em;\">\n<div class=\"wp-block-image\"><figure class=\"alignright is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/kermitmurray.com\/murray\/wp-content\/uploads\/2019\/07\/Nominal-TOC-Figure.gif\" alt=\"Nominal mass \" class=\"wp-image-2067\" width=\"310\" height=\"356\"\/><figcaption>Nominal mass from Comment on: \u201cNominal Mass?\u201d J. Am. Soc. Mass Spectrom. 28 (2017) 1737<\/figcaption><\/figure><\/div>\n\n\n\n<p>A recent correspondence [<a href=\"https:\/\/link.springer.com\/article\/10.1007%2Fs13361-017-1801-1#CR1\">1<\/a>] suggests that the current International Union of Pure and Applied Chemistry (IUPAC) recommendation [<a href=\"https:\/\/link.springer.com\/article\/10.1007%2Fs13361-017-1801-1#CR2\">2<\/a>] for the definition of&nbsp;<em>nominal mass<\/em>&nbsp;is flawed and should be expanded so that all possible isotope combinations for a molecule or ion can be assigned a whole number mass. The authors propose a revised definition for nominal mass as \u201cthe sum of the unified mass scale-based integer masses of its constituent protons and neutrons.\u201d This comment is aimed at showing that nominal mass is well defined and widely used and is an essential concept in mass spectrometry. As an alternative to redefining nominal mass, it is suggested that integer mass, defined as the sum of the mass numbers of the elements comprising a molecular ion or molecule, be used.<\/p>\n<\/div><\/div>\n<\/div><\/div>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":2067,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[134,5,88],"tags":[113,110,135,111,114,109,174,77,112],"class_list":["post-2064","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-lsu","category-publication","category-terminology","tag-exact-mass","tag-integer-mass","tag-lsu","tag-mass","tag-monoisotopic-mass","tag-nominal-mass","tag-paper","tag-publication","tag-terminology","entry"],"_links":{"self":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts\/2064","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/comments?post=2064"}],"version-history":[{"count":5,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts\/2064\/revisions"}],"predecessor-version":[{"id":2236,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/posts\/2064\/revisions\/2236"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/media\/2067"}],"wp:attachment":[{"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/media?parent=2064"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/categories?post=2064"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/kermitmurray.com\/research\/wp-json\/wp\/v2\/tags?post=2064"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}