Infrared multiphoton dissociation
From Mass Spec Terms
DRAFT DEFINITION |
Infrared multiphoton dissociation |
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A multiphoton process wherein the reactant ion is dissociated as a result of cumulative excitation of the reactant ion that absorbs a number of infrared photons in a short time. This term is particularly associated with Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry in which an ultrahigh vacuum inside the ICR (Penning) ion trap is free from collisional relaxation of the reactant ion's internal energy. |
Considered between 2004 and 2006 but not included in the 2006 PAC submission |
This is an unofficial draft definition presented for information and comment. |