Charge remote fragmentation: Difference between revisions

Latest revision as of 23:29, 3 November 2013

Charge remote fragmentation (CRF)
IUPAC RECOMMENDATIONS 2013
Fragmentation of an ion in which the cleaved bond is isolated from the apparent charge site by a distance of several bond lengths.
Related Term(s): charge-mediated fragmentation
Reference(s): A. Savagnac, H. Aurelle, C. Casas, F. Couderc, P. Gavard, D. Prome, J. C. Prome. Chem. Phys. Lipids 51, 31 (1989). (http://dx.doi.org/10.1016/0009-3084(89)90063-7 ) K. B. Tomer, N. J. Jensen, M. L. Gross, J. Whitney. Biomed. Environ. Mass Spectrom. 13, 265 (1986). (http://dx.doi.org/10.1002/bms.1200130602 )
From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.
Index of Recommended Terms

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-{{DefName|
+{{Final
-A fragmentation of an [[Even-Electron Ion|even-electron ion]] in which the bond to be cleaved lies remote from the apparent charge site. Particularly this fragmentation often occurs in a [[High-Energy Collision-Induced Dissociation|high-energy collision-induced dissociation]] process. This term is opposed to the term [[Charge-Mediated Fragmentation|charge-mediated fragmentation]].
+|acronym=(CRF)
+|def=Fragmentation of an [[ion]] in which the cleaved bond is isolated from the apparent charge site by a distance of several bond lengths.
+|rel=[[charge-mediated fragmentation]]
+|ref=A. Savagnac, H. Aurelle, C. Casas, F. Couderc, P. Gavard, D. Prome, J. C. Prome. Chem. Phys. Lipids 51, 31 (1989). (http://dx.doi.org/10.1016/0009-3084(89)90063-7 )
+K. B. Tomer, N. J. Jensen, M. L. Gross, J. Whitney. Biomed. Environ. Mass Spectrom. 13, 265 (1986). (http://dx.doi.org/10.1002/bms.1200130602 )
 }}
-== Related Terms ==
-*[[Charge Exchange Reaction]]
-*[[Charge-Induced Fragmentation]]
-*[[Charge Inversion Reaction]]
-*[[Charge Permutation Reaction]]
-*[[Charge Stripping Reaction]]
-*[[Charge Transfer Reaction]]
 [[Category:Reactions]]