Nth-generation product ion: Difference between revisions
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{{ | {{Final | ||
|acronym= | |||
|def=Deprecated: [[granddaughter ion]]. | |||
Serial [[product ion]]s from dissociation or bimolecular reaction of selected [[precursor ion]]s where n | |||
refers to the number of stages of dissociation or bimolecular reaction in a series of consecutive reactions that involve successive product ions. | |||
:Note 1: Given the sequential fragmentation scheme: M<sub>1</sub><sup>+</sup> ➞ M<sub>2</sub><sup>+</sup> ➞ M<sub>3</sub><sup>+</sup> ➞ M<sub>4</sub><sup>+</sup> ➞ M<sub>5</sub><sup>+</sup> | |||
M<sub>4</sub><sup>+</sup> is the precursor ion of M<sub>5</sub><sup>+</sup>, a 1<sup>st</sup>-generation product ion of M<sub>3</sub><sup>+</sup>, a 2<sup>nd</sup>-generation product ion of M<sub>2</sub><sup>+</sup>, and a 3<sup>rd</sup>-generation product ion of M<sub>1</sub><sup>+</sup>. | |||
|rel=[[nth-generation product ion spectrum]] | |||
|ref= P. Price. J. Am. Soc. Mass Spectrom. 2, 336 (1991). (http://dx.doi.org/10.1016/1044-0305(91)80025-3 ) | |||
G. Glish. J. Am. Soc. Mass Spectrom. 2, 349 (1991). (http://dx.doi.org/10.1016/1044-0305(91)80026-4 ) | |||
G. C. Thorne, K. D. Ballard, S. J. Gaskell. J. Am. Soc. Mass Spectrom. 1, 249 (1990). (http://dx.doi.org/10.1016/1044-0305(90)85042-K ) | |||
}} | }} | ||
{{daughter}} | |||
Latest revision as of 22:07, 24 October 2013
| IUPAC RECOMMENDATIONS 2013 |
| Nth-generation product ion |
|---|
| Deprecated: granddaughter ion.
Serial product ions from dissociation or bimolecular reaction of selected precursor ions where n refers to the number of stages of dissociation or bimolecular reaction in a series of consecutive reactions that involve successive product ions.
M4+ is the precursor ion of M5+, a 1st-generation product ion of M3+, a 2nd-generation product ion of M2+, and a 3rd-generation product ion of M1+. |
| Related Term(s): nth-generation product ion spectrum |
| Reference(s):
P. Price. J. Am. Soc. Mass Spectrom. 2, 336 (1991). (http://dx.doi.org/10.1016/1044-0305(91)80025-3 ) G. Glish. J. Am. Soc. Mass Spectrom. 2, 349 (1991). (http://dx.doi.org/10.1016/1044-0305(91)80026-4 ) G. C. Thorne, K. D. Ballard, S. J. Gaskell. J. Am. Soc. Mass Spectrom. 1, 249 (1990). (http://dx.doi.org/10.1016/1044-0305(90)85042-K ) |
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
| QUOTED TEXT FROM IUPAC RECOMMENDATIONS 2013 |
| The anthropomorphic terms for ions involved in fragmentation reactions, for example, daughter ion, have fallen into disuse after strong sentiments against the use of the term were voiced two decades ago [1][2]. The term product ion is recommended in place of daughter ion and precursor ion in place of parent ion. The use of nth-generation product ion is recommended in place of granddaughter ion and similar terms. |
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
|---|
