McLafferty rearrangement: Difference between revisions
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*[http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/onr240.htm CambridgeSoft Link] | *[http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/onr240.htm CambridgeSoft Link] | ||
*[http://masspec.scripps.edu/information/history/names/detail.html?id=12 Fred McLafferty Biography (Scripps)] | *[http://masspec.scripps.edu/information/history/names/detail.html?id=12 Fred McLafferty Biography (Scripps)] | ||
[[Category:Reactions]] | [[Category:Reactions]] | ||
Revision as of 22:31, 28 June 2006
| DRAFT DEFINITION |
| McLafferty rearrangement |
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β Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge. http://ch309c.chem.lsu.edu:16080/mswiki/images/2/2d/McLafferty_rearrangement.gif
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| Considered between 2004 and 2006 but not included in the 2006 PAC submission |
| This is an unofficial draft definition presented for information and comment. |
Orange Book Entry
This is an example of a rearrangement reaction and is defined as β - cleavage with concomitant specific transfer of a γ - hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or by an ionic mechanism and irrespective of with which fragment the charge stays.
Gold Book Entry
β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge.
