McLafferty rearrangement: Difference between revisions

From Mass Spec Terms
No edit summary
Line 1: Line 1:
{{stub}}
== [[Orange Book]] Entry ==
== [[Orange Book]] Entry ==


This is an example of a rearrangement reaction and is defined as - cleavage with concomitant specific transfer of a - hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or by an ionic mechanism and irrespective of with which fragment the charge stays.
This is an example of a rearrangement reaction and is defined as β - cleavage with concomitant specific transfer of a γ - hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or by an ionic mechanism and irrespective of with which fragment the charge stays.
 
== Proposed New Entry ==


(there is no new entry yet)


== External Links ==
== External Links ==

Revision as of 00:34, 19 January 2005

The McLafferty rearrangement page currently does not have any content, please see

All terms | IUPAC 2013 | Gold Book terms | Orange Book terms | Acronyms | Deprecated terms | Obsolete terms | Draft definitions | Stub pages


Orange Book Entry

This is an example of a rearrangement reaction and is defined as β - cleavage with concomitant specific transfer of a γ - hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or by an ionic mechanism and irrespective of with which fragment the charge stays.


External Links

IUPAC Gold Book Entry (PDF)

CambridgeSoft Link

with figure:http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/3795307.gif