Isotopomeric ion: Difference between revisions

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Isomeric ion having the same numbers of each isotopic atom but differing in their positions. Isotopomeric ions can be either configurational isomers in which two atomic isotopes exchange positions or isotopic stereoisomers. The term isotopomer is a shortening of isotopic isomer.
Isomeric ion having the same numbers of each isotopic atom but differing in their positions. Isotopomeric ions can be either configurational isomers in which two atomic isotopes exchange positions or isotopic stereoisomers. The term isotopomer is a shortening of isotopic isomer.
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Isomeric ions having the same numbers of each isotopic atom but differing in their positions within the ion. Isotopomeric ions can be either configurational isomers in which two atomic isotopes exchange positions or isotopic stereoisomers.
Note:  isotopomer is an abbreviation of isotopic isomer.
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#O. D. Sparkman. Mass Spec Desk Reference. Global View Publishing, Pittsburgh (2006).
#[[Gold Book]]
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http://goldbook.iupac.org/I03352.html
'''isotopomer'''
Isomers having the same number of each isotopic atom but differing in their positions. The term is a contraction of 'isotopic isomer'. Isotopomers can be either constitutional isomers (e.g. CH2DCH O and CH3CD O) or isotopic stereoisomers [e.g. (R)- and (S)-CH3CHDOH or (Z)- and (E)-CH3CH CHD].
Source:
PAC, 1994, 66, 1077 ([[Glossary of terms used in physical organic chemistry]] (IUPAC Recommendations 1994)) on page 1132
PAC, 1996, 68, 2193 ([[Basic terminology of stereochemistry]] (IUPAC Recommendations 1996)) on page 2211
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Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Isotopomeric ion

http://goldbook.iupac.org/I03352.html

isotopomer

Isomers having the same number of each isotopic atom but differing in their positions. The term is a contraction of 'isotopic isomer'. Isotopomers can be either constitutional isomers (e.g. CH2DCH O and CH3CD O) or isotopic stereoisomers [e.g. (R)- and (S)-CH3CHDOH or (Z)- and (E)-CH3CH CHD].

Source:

PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1132 PAC, 1996, 68, 2193 (Basic terminology of stereochemistry (IUPAC Recommendations 1996)) on page 2211

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