Charge-transfer reaction (in mass spectrometry): Difference between revisions
From Mass Spec Terms
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Reaction of an ion with a neutral species in which some or all of the charge of the reactant ion is transferred to the neutral species. | Reaction of an ion with a neutral species in which some or all of the charge of the reactant ion is transferred to the neutral species. | ||
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== Orange Book Entry == | == Orange Book Entry == | ||
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*[[Charge Exchange Reaction]] | *[[Charge Exchange Reaction]] | ||
*[[Charge-Induced Fragmentation]] | *[[Charge-Induced Fragmentation]] | ||
*[[Charge Inversion Reaction]] | *[[Charge Inversion Reaction]] | ||
*[[Charge Permutation Reaction]] | *[[Charge Permutation Reaction]] | ||
*[[Charge-Remote Fragmentation]] | *[[Charge-Remote Fragmentation]] | ||
*[[Charge Stripping Reaction]] | *[[Charge Stripping Reaction]] | ||
[[Category:Reactions]] | [[Category:Reactions]] | ||
{{DEFAULTSORT:Charge Transfer Reaction}} | {{DEFAULTSORT:Charge Transfer Reaction}} |
Revision as of 16:47, 12 July 2009
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Orange Book Entry
Orange Book
ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
Charge-transfer reaction (in mass spectrometry) |
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An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M2+, M+ and M- with a neutral species X are categorized in terms of the above definitions as follows: M2+ + X → M+ + X+ (Partial charge transfer) M+ + X → M2+ + X + e (Charge stripping) M- + X → M+ + X + 2e (Charge stripping & charge inversion) These are all ion/neutral species reactions and also charge permutation reactions. |
IUPAC 1997 Orange Book Chapter 12 |
Index of Orange Book Terms |